Beilstein J. Nanotechnol.2018,9, 384–398, doi:10.3762/bjnano.9.38
other copper(I) β-diketonatecomplexes, namely, [Cu(hfac)VTMS], [Cu(hfac)DMB], and [Cu(hfac)MHY] the atomic ratios of Cu/C/O/Si were 20–45:35–70:8–14:2–10, 25–60:15–60:5–25:-, and 13:82:3:-, respectively. As-deposited freestanding rods from FEBID experiments with [Cu(hfac)VTMS] showed small Cu
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Figure 1:
A schematic structure of investigated molecules (left) [Cu2(µ-O2CC2F5)4], (right) [Cu2(EtNH2)2(µ-O2...
Beilstein J. Nanotechnol.2014,5, 2139–2148, doi:10.3762/bjnano.5.223
) in octahedral environment were observed.
Keywords: Au(111); β-diketonatecomplexes; DFT; STM; thin films; UPS; XMCD; XPS; Introduction
A renewed interest in mononuclear metal complexes has recently arisen due to the observation that systems of this class can behave as single molecule magnets (SMMs
). Despite the high deposition rate, longer doses (t6 = 10 min and t7 = 20 min) do not produce thicker films, which confirms that saturation of the coverage has been achieved. This behaviour is fully consistent with that reported for other metal β-diketonatecomplexes. Saturation coverage has been observed
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Figure 1:
UPS spectra acquired for the Au(111) sample exposed to increasing doses of Fe(dpm)3 with low (left)...